Bobbie Grubbs and his wife, Deedra Grubbs, were arrested Friday after 10 days on the run.
They're accused of three home invasion robberies and a deadly shooting at an East Texas motel.
Deedra Grubbs is charged with aggravated robbery and burglary of a habitation.
Bobbie Grubbs is charged with capital murder in Shelby County. He also faces several charges in Harris County, including aggravated robbery.