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The incident happened around 12:30 p.m. at 6414 Skyview Dr., near Highway 290 and Beltway 8.
The 3-year-old, who has not been identified, was transported to the hospital by Life Flight. According to a tweet sent by Sheriff Ed Gonzalez, there were two adults and several of the child's siblings inside the home at the time of the incident.
Gonzalez said preliminary reports show the child somehow got a hold of the gun that was left loaded.
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The investigation remains ongoing.
TIMELINE: Children accidentally shooting themselves with guns in their homes
TIMELINE: Houston-area children that accidentally shot themselves