It began around 1am when a police officer tried to stop a stolen Dodge Charger in the 6400 block of Hillcroft.
According to investigators, the driver refused to stop and led police to the Southwest Freeway, where a gun was reportedly tossed out of the window.
Police said the driver then went down the Southwest Freeway, reaching speeds of 100mph. He tried to make a U-turn at the Dairy Ashford exit and crashed.
The driver and a passenger were arrested, and police said they found a second gun in the vehicle.
They are facing charges of felony evading and unauthorized use of a motor vehicle. The vehicle reportedly had been stolen three days ago from a park in southwest Houston.
Police also believe the men have been involved in robberies in Houston.
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