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The incident happened in the 6000 block of FM 1725 in Cleveland, Texas, shortly after 6:30 p.m.
According to the San Jacinto County Sheriff's Office, deputies were called to the area after receiving reports of a shooting.
When they arrived, deputies said a woman was found shot in the front yard, and the man was found next to her, suffering from a gunshot wound to the head.
Deputies said he was transported to a local trauma center in critical condition via medical helicopter.
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Investigators determined this was an isolated incident between the two, and there was no threat to the public.
An investigation is ongoing.