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The crash was reported on Highway 90, just east of FM-1875 Road, which was closed for several hours before it was reopened at about 3:30 p.m.
The Fort Bend County Sheriff's Office said there was a fuel leak as a result of the crash.
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SkyEye flew over the crash, where heavy skid marks could be seen on the road, and 18-wheelers veered off into the grass.
A Life Flight helicopter was also called to the scene but deputies did not provide further details about any injuries.